Acid/base responsive assembly/dis-assembly of a family of zirconium(IV) clusters with a cyclic imide-dioxime ligand.
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DOI: 10.1039/d1dt03641f
Abstract: The hydrolytically stable dioxime ligand (2Z-6Z)-piperidine-2,6-dione (H3pidiox) acts as a strong chelator mainly with hard metals in high oxidation states, a pre-requisite for potential applications in metal sequestering processes from aqueous solutions. Reaction of ZrCl4… read more here.
Keywords: pentanuclear zroc; dioxime ligand; zirconium; dis assembly ... See more keywords