LiN5: A novel pentazolate salt with high nitrogen content
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2021.132399
Abstract: Abstract A high energy cyclo-pentazolate (cyclo-N5-) salt with 90.98 % nitrogen content, LiN5, was synthesized by a simple metathesis reaction of AgN5 and LiCl in deionized water. It was characterized by 15N nuclear magnetic resonance,… read more here.
Keywords: salt; lin5; nitrogen content; pentazolate ... See more keywords
Direct formation of [NH4]N3 from a pentazolate salt through single-crystal to single-crystal transformation
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.02.001
Abstract: Abstract In the area of polynitrogen anions, the only stable species synthesized as yet are the azide anion (N3−) and the pentazolate anion (cyclo-N5−). We here describe an unprecedented example of a spontaneous single-crystal to… read more here.
Keywords: crystal single; single crystal; crystal transformation; pentazolate ... See more keywords
High-Pressure Synthesis and Stability Enhancement of Lithium Pentazolate.
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DOI: 10.1021/acs.inorgchem.2c00112
Abstract: The pentazolate anion, cyclo-N5-, has received extensive attention as a new generation of energetic species for explosive or propulsion applications. Binary pentazolate compounds have been obtained under high-pressure conditions and their stability enhancement is crucial… read more here.
Keywords: pentazolate; pressure; lithium; stability enhancement ... See more keywords
Synthesis and Characterization of cyclo-Pentazolate Salts of NH4+, NH3OH+, N2H5+, C(NH2)3+, and N(CH3)4.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b05106
Abstract: A breakthrough in polynitrogen chemistry was recently achieved by our bulk synthesis of (N5)6(H3O)3(NH4)4Cl in which the cyclo-pentazolate anions were stabilized extensively by hydrogen bridges with the NH4+ and OH3+ cations. Significant efforts have been… read more here.
Keywords: pentazolate salts; nh3oh n2h5; ch3; pentazolate ... See more keywords