Rhodium-Catalyzed Synthesis of Peptide Polysulfides by Insertion of Sulfur into Unprotected Peptide Disulfides.
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DOI: 10.1021/acs.orglett.2c03257
Abstract: A rhodium-catalyzed insertion of sulfur into unprotected peptide disulfides in aqueous solvents has been developed, which yields mixtures of trisulfides and tetrasulfides. This method can be applied to peptides containing amino acids such as Gly,… read more here.
Keywords: unprotected peptide; rhodium catalyzed; sulfur unprotected; peptide disulfides ... See more keywords