Articles with "perchloric acid" as a keyword



Perchloric Acid, an Effective Catalyst for Thermosetting Self‐Crosslinking Hydroxy Acrylic Resins

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Published in 2025 at "Journal of Applied Polymer Science"

DOI: 10.1002/app.58087

Abstract: Ethyl acrylate (EA)–2‐hydroxyethyl acrylate (HEA) and ethyl acrylate (EA)–4‐hydroxybutyl acrylate (HBA) containing acrylic resins were crosslinked by the action of perchloric acid. The crosslinking is based on the intermediate formation of alkyl perchlorate esters from… read more here.

Keywords: acrylic resins; perchloric acid; amounts perchloric; acid effective ... See more keywords

Stability constants and spectroscopic properties of thorium(IV)-arsenazo III complexes in perchloric acid

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Published in 2018 at "Journal of Radioanalytical and Nuclear Chemistry"

DOI: 10.1007/s10967-018-6342-y

Abstract: The complexation of thorium with arsenazo III in perchloric acid was quantitatively investigated with ultraviolet–visible (UV–Vis) absorption spectroscopy. The UV–Vis absorption of both 1:1 and 1:2 (thorium to arsenazo III) complexes in perchloric acid were… read more here.

Keywords: thorium arsenazo; complexes perchloric; arsenazo iii; iii complexes ... See more keywords

Oxidation of the drug tiopronin by Cerium(IV) in perchloric acid media: Kinetic and mechanistic analyses

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Published in 2017 at "Journal of Molecular Liquids"

DOI: 10.1016/j.molliq.2017.09.009

Abstract: Abstract Although several analytical methods based on the Ce(IV) oxidations were developed for determinations of the drug tiopronin (MPG) and some biothiols, the kinetic and mechanistic aspects of oxidations of the thiol-containing molecules by Ce(IV)… read more here.

Keywords: drug tiopronin; kinetic mechanistic; acid media; rate ... See more keywords

Oxidative degradation of neomycin and streptomycin by cerium(IV) in sulphuric and perchloric acid solutions

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Published in 2020 at "Journal of Molecular Liquids"

DOI: 10.1016/j.molliq.2020.113439

Abstract: Abstract Degradation kinetics of antibiotics neomycin and streptomycin was explored spectrophotometrically via their oxidation by cerium(IV) in both sulphuric and perchloric acids. The oxidation reactions demonstrated a 1:8 stoichiometry (antibiotic:cerium(IV)). The kinetics of the reactions… read more here.

Keywords: cerium; sulphuric perchloric; oxidation; streptomycin ... See more keywords

Electrochemical Production of Hydrogen Peroxide in Perchloric Acid Supporting Electrolytes for the Synthesis of Chlorine Dioxide

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Published in 2022 at "Industrial & Engineering Chemistry Research"

DOI: 10.1021/acs.iecr.1c04845

Abstract: This work focuses on the electrochemical production of hydrogen peroxide in supporting electrolytes containing perchlorate ions for being used as a reagent in the reduction of chlorates to produce chlorine dioxide, as a first step… read more here.

Keywords: hydrogen peroxide; perchloric acid; chlorine dioxide; production hydrogen ... See more keywords

Interaction in the nickel perchlorate–acetamide–perchloric acid–water system at 25°С

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Published in 2017 at "Russian Journal of Inorganic Chemistry"

DOI: 10.1134/s0036023617090066

Abstract: Heterogeneous equilibria in the nickel perchlorate–acetamide–perchloric acid–water quaternary system at 25°С were studied by studying solubility. The crystallization regions were determined for the initial solid components, eutonic compositions of the ternary systems constituting the quaternary… read more here.

Keywords: system; acetamide perchloric; perchlorate acetamide; nickel perchlorate ... See more keywords

Experimental, Monte Carlo and Molecular Dynamic Study on Corrosion Inhibition of Mild Steel by Pyridine Derivatives in Aqueous Perchloric Acid

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Published in 2020 at "Electrochemistry"

DOI: 10.3390/electrochem1020013

Abstract: The corrosion of mild steel in aqueous perchloric acid solution was studied in the presence and absence of four different pyridine derivatives. Electrochemical measurements point out that these molecules inhibit the corrosion of mild steel… read more here.

Keywords: mild steel; monte carlo; corrosion; aqueous perchloric ... See more keywords