Toward Perfect Regiocontrol for β-Selective Cyclopolymerization Using a Ru-Based Olefin Metathesis Catalyst
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DOI: 10.1021/acs.macromol.8b00969
Abstract: Ru-based metathesis catalysts employed in cyclopolymerization (CP) of 1,6-heptadiyne derivatives have promoted regioselective α-addition to alkynes, forming various conjugated polyenes containing exclusively five-membered repeat units. Recently, we discovered that a new chelated Ru catalyst could… read more here.
Keywords: perfect regiocontrol; toward perfect; cyclopolymerization; catalyst ... See more keywords