Enhanced Relative Stability of Metallabenzenes versus Metallocenes upon Ring Perfluorination: Nickel, Palladium, and Platinum Systems
Sign Up to like & getrecommendations! Published in 2017 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.201700810
Abstract: Perfluorination of one η5-C5H5 ring in the MC10H10 system (M = Ni, Pd, Pt) to give an MC10H5F5 system greatly destabilizes structures containing a perfluorinated pentahapto η5-C5F5 ring. As a result, the metallapentafluorobenzene structures (η5-C5H5)(MC5F5)… read more here.
Keywords: perfluorination; energy; palladium platinum; nickel palladium ... See more keywords
Pyridine’s ring normal modes as footprints for its derivatives: The impact of perfluorination
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2020.109716
Abstract: Abstract The effects of full fluorination of pyridine, quinoline, 1,8-naphthyridine and 1,10-phenathroline were investigated through quantum mechanical calculations using pyridine as a reference. Among their vibrational normal modes, 6 out of 7 ring related normal… read more here.
Keywords: pyridine ring; modes footprints; ring normal; perfluorination ... See more keywords