Regioselective Aromatic Perfluoro-tert-butylation Using Perfluoro-tert-butyl Phenyl Sulfone and Arynes.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10479
Abstract: The selective introduction of perfluoro-tert-butyl group (PFtB, the bulkier analogue of CF3 group) into arenes has long been sought after but remains a formidable task. We herein report the first general synthetic protocol to realize… read more here.
Keywords: perfluoro tert; tert butylation; perfluoro; aromatic perfluoro ... See more keywords
Molecular engineering low-surface energy membranes by grafting perfluoro-tert-butoxy chains containing fluorous silica aerogels
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DOI: 10.1039/d0gc00593b
Abstract: The recent attention on perfluorinated superhydrophobic membranes has been accompanied by growing concerns over the potential degradation of longer than C6-perfluoroalkyl chain containing compounds in the environment to form bioaccumulating perfluoroalkyl acids. While maintaining the… read more here.
Keywords: tert butoxy; surface; perfluoro tert; low surface ... See more keywords