Merging photoredox catalysis with allylboration. The photochemical perfluoroalkylation of unsaturated potassium alkyltrifluoroborates and synthesis of fluorinated alcohols
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DOI: 10.1016/j.tetlet.2018.05.086
Abstract: Abstract The development of a visible light-mediated atom transfer radical addition (ATRA) of perfluoroalkyl iodides to potassium 1-penten-5-yl-, vinyl- and allyltrifluoroborates using the reductive quenching of [Ru(bpy) 3 ]Cl 2 or [Ru(bpy) 3 ](PF 6… read more here.
Keywords: potassium; perfluoroalkyl iodides; merging photoredox; fluorinated alcohols ... See more keywords