Synthesis of Aryl Perfluorocyclopropyl Ethers via [2 + 1] Cyclopropanation Using TMSCF2Br Reagent.
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DOI: 10.1021/acs.orglett.2c00958
Abstract: Aryl perfluorocyclopropyl ethers have been synthesized for the first time by [2 + 1] cyclopropanation between aryl trifluorovinyl ethers and a commercially available TMSCF2Br reagent. This cycloaddition reaction between two fluorine-containing reactants proceeds smoothly in… read more here.
Keywords: aryl perfluorocyclopropyl; tmscf2br reagent; perfluorocyclopropyl ethers; cyclopropanation ... See more keywords