Synthetic access to an elusive high-temperature perfluoroisopropenyl ether prepolymer for radical copolymerization.
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DOI: 10.1039/c8cc05241g
Abstract: A perfluoroisopropenyl ether terminated oligo(hexafluoropropylene oxide), a perfluoropolyalkyl ether macromonomer for radical copolymerization, has been prepared. The synthesis was achieved through a carefully controlled defluorination of a highly unstable lithium perfluorocarbanion intermediate. Several undesired pathways… read more here.
Keywords: synthetic access; radical copolymerization; perfluoroisopropenyl ether; access elusive ... See more keywords