Probing Donor Acceptor Interactions of Chalcogenide Supported Fluorophosphonium Ions Using peri‐Substituted Acenaphthyl Scaffolds
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DOI: 10.1002/ejic.202400536
Abstract: The fluorination of the peri‐substituted acenaphthyl scaffolds 5‐PhE‐Ace‐6‐PPh2 (1E, E = O, S, Se, Te) using XeF2 afforded the difluorinated products 5‐PhE‐Ace‐6‐PF2Ph2 (2E, E = O, S, Se, Te) and tetrafluorinated products 5‐PhEF2‐Ace‐6‐PF2Ph2 (3E, E… read more here.
Keywords: fluorophosphonium ions; supported fluorophosphonium; acenaphthyl scaffolds; chalcogenide supported ... See more keywords
Synthesis and Structural Studies of peri-Substituted Acenaphthenes with Tertiary Phosphine and Stibine Groups
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DOI: 10.3390/molecules29081841
Abstract: Two mixed peri-substituted phosphine-chlorostibines, Acenap(PiPr2)(SbPhCl) and Acenap(PiPr2)(SbCl2) (Acenap = acenaphthene-5,6-diyl) reacted cleanly with Grignard reagents or nBuLi to give the corresponding tertiary phosphine-stibines Acenap(PiPr2)(SbRR’) (R, R’ = Me, iPr, nBu, Ph). In addition, the Pt(II)… read more here.
Keywords: tertiary phosphine; phosphine stibines; phosphine stibine; peri substituted ... See more keywords