Conformational Control of σ-Interference Effects in the Conductance of Permethylated Oligosilanes.
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DOI: 10.1021/jacs.4c12676
Abstract: As silicon-based integrated circuits continue to shrink, their molecular characteristics become more pronounced. However, the structure-property relationship of silicon-based molecular junctions remains to be elucidated. Here, an intuitive explanation of the effects of backbone dihedral… read more here.
Keywords: dihedral angles; mcos; permethylated oligosilanes; conductance ... See more keywords