Synergistic Influence of d0 (Nb5+) and d10 (Cd2+) Cations in Stabilizing Noncentrosymmetric Dion-Jacobson Layered Perovskites, A'Cd2Nb3O10 (A' = Rb, Cs).
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DOI: 10.1021/acs.inorgchem.0c00291
Abstract: New Dion-Jacobson (n = 3) layered perovskites, A'Cd2Nb3O10 (A' = Rb, Cs), have been synthesized by a solid-state method. Powder X-ray diffraction measurements confirm the noncentrosymmetric orthorhombic (space group Ima2) structures for both rubidium- and… read more here.
Keywords: jacobson layered; dion jacobson; layered perovskites; perovskites cd2nb3o10 ... See more keywords