Nitration-Peroxidation of Alkenes: A Selective Approach to β-Peroxyl Nitroalkanes.
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DOI: 10.1021/acs.orglett.9b00266
Abstract: Nitration-peroxidation of alkenes for the synthesis of β-peroxyl nitroalkanes has been developed by using tert-butyl nitrite and tert-butyl hydroperoxide. The method presents a new and selective difunctionalization of alkenes to introduce a nitro group and… read more here.
Keywords: nitration peroxidation; peroxyl; peroxidation alkenes; alkenes selective ... See more keywords
Copper-catalyzed trifluoromethylthiolation-peroxidation of alkenes and allenes
Sign Up to like & getrecommendations! Published in 2020 at "Organic chemistry frontiers"
DOI: 10.1039/d0qo00533a
Abstract: Trifluoromethylthiolation-peroxidation of alkenes using AgSCF3 and tert-butyl hydroperoxide has been developed in the presence of a copper catalyst. The method exhibits a broad alkene scope with excellent regio- and chemo-selectivities, providing a variety of β-trifluoromethylthio… read more here.
Keywords: catalyzed trifluoromethylthiolation; peroxidation alkenes; trifluoromethylthiolation; trifluoromethylthiolation peroxidation ... See more keywords