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Published in 2018 at "Organic chemistry frontiers"
DOI: 10.1039/c8qo00797g
Abstract: The catalytic alkylation–peroxidation of α-carbonyl imines or ketones was enabled by a simple copper salt under very mild reaction conditions. The transformations involved radical-mediated Csp3–H functionalization and afforded stable α-amino or α-alkyloxyl peroxides in good…
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Keywords:
alkylation peroxidation;
copper salt;
peroxidation carbonyl;
radical mediated ... See more keywords