A novel manganese(III)-peroxo complex bearing a proline-derived pentadentate aminobenzimidazole ligand
Sign Up to like & getrecommendations! Published in 2018 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2018.04.036
Abstract: Abstract Manganese(III)-peroxo complexes are invoked as key intermediates in the enzymatic cycles of Mn-containing enzymes, and the synthesis of reactive manganese(III)-peroxo complexes with rationally designed ligand has been of great interest in the communities of… read more here.
Keywords: manganese iii; pentadentate aminobenzimidazole; aminobenzimidazole ligand; peroxo complex ... See more keywords
A Mn(iv)-peroxo complex in the reactions with proton donors.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00649d
Abstract: Protons play an important role in promoting O-O or M-O bond cleavage of metal-peroxo complexes. Treatment of side-on O2-bound [PPN][MnIV(TMSPS3)(O2)] (1, PPN = bis(triphenylphosphine)iminium and TMSPS3H3 = 2,2',2''-trimercapto-3,3',3''-tris(trimethylsilyl)triphenylphosphine) with perchloric acid (HClO4) in the presence… read more here.
Keywords: complex reactions; proton donors; reactions proton; peroxo complex ... See more keywords