A Porphyrinic Donor-Acceptor Conjugated Porous Polymer as Highly Efficient Photocatalyst for PET-RAFT Polymerization.
Sign Up to like & getrecommendations! Published in 2022 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202200173
Abstract: Heterogeneous catalysts offer a highly desirable platform for exploring environmental-benign transformation systems, yet, they typically suffer from significant loss of catalytic efficiency compared with their homogeneous counterparts. In this study, we report the facile synthesis… read more here.
Keywords: pet raft; pet; conjugated porous; porous polymer ... See more keywords
PET-RAFT Polymerization of Star Polymers with Folded ortho-Phenylene Cores.
Sign Up to like & getrecommendations! Published in 2023 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202300094
Abstract: ortho-Phenylenes are one of simplest classes of aromatic foldamers, adopting helical geometries because of aromatic stacking interactions. The folding and misfolding of ortho-phenylenes are slow on the NMR timescale at or below room temperature, allowing… read more here.
Keywords: star polymers; pet raft; spectroscopy; ortho phenylene ... See more keywords
Automated Multi- and Block-Copolymer Writing in Mesoporous Films Using Visible-Light PET-RAFT and a Microscope.
Sign Up to like & getrecommendations! Published in 2023 at "Small"
DOI: 10.1002/smll.202207762
Abstract: For high throughput applications, e.g., in the context of sensing especially when being combined with machine learning, large sample numbers in acceptable production time are required. This needs automated synthesis and material functionalization concepts ideally… read more here.
Keywords: polymer; pet raft; writing mesoporous; block ... See more keywords
Unleashing the Power of PET-RAFT Polymerization: Journey from Porphyrin-Based Photocatalysts to Combinatorial Technologies and Advanced Bioapplications.
Sign Up to like & getrecommendations! Published in 2024 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.3c01356
Abstract: The emergence of photoinduced energy/electron transfer-reversible addition-fragmentation chain transfer polymerization (PET-RAFT) not only revolutionized the field of photopolymerization but also accelerated the development of porphyrin-based photocatalysts and their analogues. The continual expansion of the monomer… read more here.
Keywords: porphyrin based; polymerization; raft polymerization; pet raft ... See more keywords
Dual Roles of Amino Functionalized Silicon Quantum Dots (SiQDs) for Visible Light-Induced Surface Initiated PET-RAFT Polymerization on Substrates.
Sign Up to like & getrecommendations! Published in 2020 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.0c12299
Abstract: Silicon quantum dots (SiQDs) are explored for the first time as an efficient photocatalysts for visible-light-regulated reversible addition-fragmentation chain-transfer (RAFT) polymerization. The fluorescence quenching confirmed the photoinduced electron transfer (PET) between SiQDs and RAFT reagents. Besides… read more here.
Keywords: polymerization; raft; pet raft; surface ... See more keywords
Ultrasensitive miRNA-21 Biosensor Based on Zn(TCPP) PET-RAFT Polymerization Signal Amplification and Multiple Logic Gate Molecular Recognition.
Sign Up to like & getrecommendations! Published in 2023 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.3c02428
Abstract: Quantitative measurement of microRNAs (miRNAs) is extremely important in plenty of biomedical applications especially cancer diagnosis but remains a great challenge. In this work, we developed a logic gate recognition biosensing platform based on the… read more here.
Keywords: recognition; pet raft; signal amplification; raft ... See more keywords
Application of oxygen tolerant PET-RAFT to polymerization-induced self-assembly
Sign Up to like & getrecommendations! Published in 2017 at "Polymer Chemistry"
DOI: 10.1039/c7py00442g
Abstract: The presence of oxygen during controlled/living radical polymerization (CLRP) can lead to a number of undesirable behaviours such as long inhibition periods and slow polymerization rates. Photoinduced Electron/Energy Transfer-Reversible Addition–Fragmentation chain Transfer (PET-RAFT) polymerization has… read more here.
Keywords: pet raft; oxygen; raft polymerization; polymerization ... See more keywords
In-situ PET-RAFT polymerization to prepare guanidine-and-carbohydrate modified ZnO nanoparticles
Sign Up to like & getrecommendations! Published in 2024 at "Polymer Chemistry"
DOI: 10.1039/d4py00223g
Abstract: ZnO-polymer core-shell nanoparticles were successfully prepared using a simple in-situ open-to-air PET-RAFT method. The utilization of vinyltriethoxysilane (VTES) modified ZnO NPs as catalysts for polymerization, along with the grafting of... read more here.
Keywords: modified zno; raft polymerization; pet raft; situ pet ... See more keywords
Fabrication of PAA-co-PNIPAm brushes via surface-initiated-PET-RAFT polymerization and investigation of their dual responsive behavior
Sign Up to like & getrecommendations! Published in 2025 at "RSC Advances"
DOI: 10.1039/d5ra06000a
Abstract: Stimuli-responsive polymers have attracted considerable attention because they can alter their chemical structures or physical properties in response to external triggers. Such smart polymers have found applications in various fields, including sensors, drug delivery, water… read more here.
Keywords: around wca; pnipam; responsive behavior; transition ... See more keywords
PET-RAFT Polymerization Catalyzed by Small Organic Molecule under Green Light Irradiation
Sign Up to like & getrecommendations! Published in 2019 at "Polymers"
DOI: 10.3390/polym11050892
Abstract: Photocatalyzed polymerization using organic molecules as catalysts has attracted broad interest because of its easy operation in ambient environments and low toxicity compared with metallic catalysts. In this work, we reported that 4,7-di(thiophen-2-yl)benzo[c][1,2,5]thiadiazole (DTBT) can… read more here.
Keywords: polymerization; pet raft; green light; raft polymerization ... See more keywords