Microwave‐Assisted Synthesis and Transformations of Cationic CpRu(II)(naphthalene) and CpRu(II)(naphthoquinone) Complexes
Sign Up to like & getrecommendations! Published in 2019 at "Helvetica Chimica Acta"
DOI: 10.1002/hlca.201900076
Abstract: Details of the direct synthesis of cationic Ru(II)(η5‐Cp)(η6‐arene) complexes from ruthenocene using microwave heating are reported. Developed for the important catalyst precursor [Ru(II)(η5‐Cp)(η6‐1‐4,4a,8a‐naphthalene)][PF6] reaction time could be shortened from three days to 15 min. The method… read more here.
Keywords: synthesis; microwave assisted; transformations cationic; assisted synthesis ... See more keywords
Ruthenium-based PACT agents based on bisquinoline chelates: synthesis, photochemistry, and cytotoxicity
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Biological Inorganic Chemistry"
DOI: 10.1007/s00775-021-01882-8
Abstract: Graphic abstract The known ruthenium complex [Ru(tpy)(bpy)(Hmte)](PF6)2 ([1](PF6)2, where tpy = 2,2’:6’,2″-terpyridine, bpy = 2,2’-bipyridine, Hmte = 2-(methylthio)ethanol) is photosubstitutionally active but non-toxic to cancer cells even upon light irradiation. In this work, the two analogs complexes [Ru(tpy)(NN)(Hmte)](PF6)2, where NN = 3,3'-biisoquinoline (i-biq,… read more here.
Keywords: ruthenium; pf6; pf6 pf6; cytotoxicity ... See more keywords
Transition metal copper composite ionic liquid self-built ratiometric sensor for the detection of paracetamol
Sign Up to like & getrecommendations! Published in 2021 at "Analytica Chimica Acta"
DOI: 10.1016/j.aca.2021.338992
Abstract: Abstract In this paper, a MOF derivative Cu-PF6-MOF composed of transition metal copper and ionic liquid [BMIM] PF6 was used to construct a ratiometric electrochemical sensor for paracetamol detection. Cu-PF6-MOF was synthesized by chemical bath… read more here.
Keywords: pf6; ionic liquid; paracetamol; transition metal ... See more keywords
Structures of 1,1′,3,3′-tetra(2-methyl-2-nonyl)ferrocenium(1+) salts of CB11H12−, B12F122−, BF4−, PF6−, and ClO3−
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.02.003
Abstract: Abstract The interdigitated and layered structures of the tetraalkylferrocenium salts [DEC][CB11H12], [DEC]2[B12F12], [DEC][BF4], [DEC][PF6], and [DEC][ClO3] were determined by single-crystal X-ray diffraction (DEC+ = 1,1′,3,3′-tetrakis(2-methyl-2-nonyl)ferrocenium(1+)). The structures of the salts of the two smaller anions were similar… read more here.
Keywords: dec; methyl nonyl; ferrocenium; clo3 ... See more keywords
Synthesis of iron(III)-carbonyl complex with variable wavelength range for CO release depending on protonation and deprotonation of axial phosphorous ligands
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2021.121843
Abstract: Abstract N,C,S-pincer iron(III) carbonyl complexes with two phosphorus ligands—trans-[Fe(L-κ3N,C,S)(CO)(PR3)2]PF6 ([1]PF6, R = Me; [ 2 ]PF6, R = OEt) are light-inducible CO releasers under ambient conditions. Optical wavelength ranges corresponding to such a CO release depend on the phosphorous… read more here.
Keywords: phosphorous ligands; pf6; iron iii; iii carbonyl ... See more keywords
Vapor-liquid equilibrium of 2,3,3,3-tetrafluoroprop-1-ene with 1-butyl-3-methylimidazolium hexafluorophosphate, 1-hexyl-3-methyl imidazolium hexafluorophosphate, and 1-octyl-3-methylimidazolium hexafluorophosphate
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2018.03.112
Abstract: Abstract In this work, we measured the vapor-liquid equilibrium of 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) in three ionic liquids, including 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim][PF6]), 1-hexyl-3-methylimidazolium hexafluorophosphate ([Hmim][PF6]), and 1-octyl-3-methylimidazolium hexafluorophosphate ([Omim][PF6]). The phase equilibrium data were reported from 283.15 K… read more here.
Keywords: vapor liquid; hexafluorophosphate; pf6; equilibrium ... See more keywords
Hypervalent Phosphorus(V) Porphyrins with meso-Methoxyphenyl Substituents: Significance of the Number and Position of Methoxy Groups in Promoting Intramolecular Charge Transfer.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01648
Abstract: To study the photophysical and redox properties as a function of meso-aryl units, a series of hypervalent phosphorus(V) porphyrins, PP(OMe)2·PF6, PMP(OMe)2·PF6, PDMP(OMe)2·PF6, P345TMP(OMe)2·PF6, and P246TMP(OMe)2·PF6, with phenyl (P), 4-methoxyphenyl (MP), 3,5-dimethoxyphenyl (DMP), 3,4,5-trimethoxyphenyl (345TMP), and… read more here.
Keywords: hypervalent phosphorus; methoxy groups; pf6; phosphorus porphyrins ... See more keywords
Two-Electron-Induced Reorganization of Cobalt Coordination and Metal-Ligand Cooperative Redox Shifting Co(I) Reactivity toward CO2 Reduction.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04071
Abstract: Electrochemical reorganization of complex structures is directly related to catalytic reactivity; thus, the geometric changes of catalysts induced by electron transfer should be considered to scrutinize the reaction mechanism. Herein, we studied electron-induced reorganization patterns… read more here.
Keywords: ligand; pf6; ch3cn pf6; electron ... See more keywords
CO Release from N,C,S-Pincer Iron(III) Carbonyl Complexes Induced by Visible-to-NIR Light Irradiation: Mechanistic Insight into Effects of Axial Phosphorus Ligands.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01407
Abstract: Light-induced CO release from newly synthesized N,C,S-pincer iron(III) carbonyl complexes with two phosphorus ligands- trans-[Fe(L-κ3 N,C,S)(CO)(PR2R')2]PF6 ([1]PF6, R = Me, R' = Ph; [2]PF6, R = R' = Me; [3]PF6, R = R' = OEt)-were… read more here.
Keywords: pf6; pf6 pf6; carbonyl complexes; iii carbonyl ... See more keywords
Synthesis, Characterization, Cytotoxic Activity, andMetabolic Studies of Ruthenium(II) Polypyridyl Complexes ContainingFlavonoid Ligands
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.9b03562.s001
Abstract: Four novel monocationic Ru(II) polypyridyl complexes were synthesized with the general formula [Ru(DIP)2flv]X, where DIP is 4,7-diphenyl-1,10-phenanthroline, flv stands for the flavonoid ligand (5-hydroxyflavone in [Ru(DIP)2(5-OHF)](PF6), genistein in [Ru(DIP)2(gen)](PF6), chrysin in [Ru(DIP)2(chr)](OTf), and morin in… read more here.
Keywords: pf6; activity; dip; polypyridyl complexes ... See more keywords
Luminescent Pt(II) complexes featuring imidazolylidene–pyridylidene and dianionic bipyrazolate: from fundamentals to OLED fabrications
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Materials Chemistry C"
DOI: 10.1039/c6tc05154e
Abstract: Pt(II) complexes bearing imidazolylidene–pyridylidene (impy) and dianionic biazolate chelates were synthesized, for which the end products depend on the alkyl substituents of the impy chelate. Treatment of Pt(DMSO)2Cl2 with dimethyl substituted imidazolium–pyridinium pro-ligand Me2impy(PF6)2, followed… read more here.
Keywords: pyridylidene; luminescent complexes; pf6; imidazolylidene pyridylidene ... See more keywords