Microwave‐Assisted Synthesis and Transformations of Cationic CpRu(II)(naphthalene) and CpRu(II)(naphthoquinone) Complexes
Sign Up to like & getrecommendations! Published in 2019 at "Helvetica Chimica Acta"
DOI: 10.1002/hlca.201900076
Abstract: Details of the direct synthesis of cationic Ru(II)(η5‐Cp)(η6‐arene) complexes from ruthenocene using microwave heating are reported. Developed for the important catalyst precursor [Ru(II)(η5‐Cp)(η6‐1‐4,4a,8a‐naphthalene)][PF6] reaction time could be shortened from three days to 15 min. The method… read more here.
Keywords: synthesis; microwave assisted; transformations cationic; assisted synthesis ... See more keywords
Ruthenium-based PACT agents based on bisquinoline chelates: synthesis, photochemistry, and cytotoxicity
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Biological Inorganic Chemistry"
DOI: 10.1007/s00775-021-01882-8
Abstract: Graphic abstract The known ruthenium complex [Ru(tpy)(bpy)(Hmte)](PF6)2 ([1](PF6)2, where tpy = 2,2’:6’,2″-terpyridine, bpy = 2,2’-bipyridine, Hmte = 2-(methylthio)ethanol) is photosubstitutionally active but non-toxic to cancer cells even upon light irradiation. In this work, the two analogs complexes [Ru(tpy)(NN)(Hmte)](PF6)2, where NN = 3,3'-biisoquinoline (i-biq,… read more here.
Keywords: ruthenium; pf6; pf6 pf6; cytotoxicity ... See more keywords
Transition metal copper composite ionic liquid self-built ratiometric sensor for the detection of paracetamol
Sign Up to like & getrecommendations! Published in 2021 at "Analytica Chimica Acta"
DOI: 10.1016/j.aca.2021.338992
Abstract: Abstract In this paper, a MOF derivative Cu-PF6-MOF composed of transition metal copper and ionic liquid [BMIM] PF6 was used to construct a ratiometric electrochemical sensor for paracetamol detection. Cu-PF6-MOF was synthesized by chemical bath… read more here.
Keywords: pf6; ionic liquid; paracetamol; transition metal ... See more keywords
Structures of 1,1′,3,3′-tetra(2-methyl-2-nonyl)ferrocenium(1+) salts of CB11H12−, B12F122−, BF4−, PF6−, and ClO3−
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.02.003
Abstract: Abstract The interdigitated and layered structures of the tetraalkylferrocenium salts [DEC][CB11H12], [DEC]2[B12F12], [DEC][BF4], [DEC][PF6], and [DEC][ClO3] were determined by single-crystal X-ray diffraction (DEC+ = 1,1′,3,3′-tetrakis(2-methyl-2-nonyl)ferrocenium(1+)). The structures of the salts of the two smaller anions were similar… read more here.
Keywords: dec; methyl nonyl; ferrocenium; clo3 ... See more keywords
Synthesis of iron(III)-carbonyl complex with variable wavelength range for CO release depending on protonation and deprotonation of axial phosphorous ligands
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2021.121843
Abstract: Abstract N,C,S-pincer iron(III) carbonyl complexes with two phosphorus ligands—trans-[Fe(L-κ3N,C,S)(CO)(PR3)2]PF6 ([1]PF6, R = Me; [ 2 ]PF6, R = OEt) are light-inducible CO releasers under ambient conditions. Optical wavelength ranges corresponding to such a CO release depend on the phosphorous… read more here.
Keywords: phosphorous ligands; pf6; iron iii; iii carbonyl ... See more keywords
Vapor-liquid equilibrium of 2,3,3,3-tetrafluoroprop-1-ene with 1-butyl-3-methylimidazolium hexafluorophosphate, 1-hexyl-3-methyl imidazolium hexafluorophosphate, and 1-octyl-3-methylimidazolium hexafluorophosphate
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2018.03.112
Abstract: Abstract In this work, we measured the vapor-liquid equilibrium of 2,3,3,3-tetrafluoroprop-1-ene (R1234yf) in three ionic liquids, including 1-butyl-3-methylimidazolium hexafluorophosphate ([Bmim][PF6]), 1-hexyl-3-methylimidazolium hexafluorophosphate ([Hmim][PF6]), and 1-octyl-3-methylimidazolium hexafluorophosphate ([Omim][PF6]). The phase equilibrium data were reported from 283.15 K… read more here.
Keywords: vapor liquid; hexafluorophosphate; pf6; equilibrium ... See more keywords
Hypervalent Phosphorus(V) Porphyrins with meso-Methoxyphenyl Substituents: Significance of the Number and Position of Methoxy Groups in Promoting Intramolecular Charge Transfer.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01648
Abstract: To study the photophysical and redox properties as a function of meso-aryl units, a series of hypervalent phosphorus(V) porphyrins, PP(OMe)2·PF6, PMP(OMe)2·PF6, PDMP(OMe)2·PF6, P345TMP(OMe)2·PF6, and P246TMP(OMe)2·PF6, with phenyl (P), 4-methoxyphenyl (MP), 3,5-dimethoxyphenyl (DMP), 3,4,5-trimethoxyphenyl (345TMP), and… read more here.
Keywords: hypervalent phosphorus; methoxy groups; pf6; phosphorus porphyrins ... See more keywords
Two-Electron-Induced Reorganization of Cobalt Coordination and Metal-Ligand Cooperative Redox Shifting Co(I) Reactivity toward CO2 Reduction.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c04071
Abstract: Electrochemical reorganization of complex structures is directly related to catalytic reactivity; thus, the geometric changes of catalysts induced by electron transfer should be considered to scrutinize the reaction mechanism. Herein, we studied electron-induced reorganization patterns… read more here.
Keywords: ligand; pf6; ch3cn pf6; electron ... See more keywords
CO Release from N,C,S-Pincer Iron(III) Carbonyl Complexes Induced by Visible-to-NIR Light Irradiation: Mechanistic Insight into Effects of Axial Phosphorus Ligands.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01407
Abstract: Light-induced CO release from newly synthesized N,C,S-pincer iron(III) carbonyl complexes with two phosphorus ligands- trans-[Fe(L-κ3 N,C,S)(CO)(PR2R')2]PF6 ([1]PF6, R = Me, R' = Ph; [2]PF6, R = R' = Me; [3]PF6, R = R' = OEt)-were… read more here.
Keywords: pf6; pf6 pf6; carbonyl complexes; iii carbonyl ... See more keywords
Synthesis, Characterization, Cytotoxic Activity, andMetabolic Studies of Ruthenium(II) Polypyridyl Complexes ContainingFlavonoid Ligands
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.9b03562.s001
Abstract: Four novel monocationic Ru(II) polypyridyl complexes were synthesized with the general formula [Ru(DIP)2flv]X, where DIP is 4,7-diphenyl-1,10-phenanthroline, flv stands for the flavonoid ligand (5-hydroxyflavone in [Ru(DIP)2(5-OHF)](PF6), genistein in [Ru(DIP)2(gen)](PF6), chrysin in [Ru(DIP)2(chr)](OTf), and morin in… read more here.
Keywords: pf6; activity; dip; polypyridyl complexes ... See more keywords
A Highly Electrostrictive Salt Cocrystal and the Piezoelectric Nanogenerator Application of Its 3D-Printed Polymer Composite
Sign Up to like & getrecommendations! Published in 2024 at "ACS Applied Materials & Interfaces"
DOI: 10.1021/acsami.4c03349
Abstract: Ionic cocrystals with hydrogen bonding can form exciting materials with enhanced optical and electronic properties. We present a highly moisture-stable ammonium salt cocrystal [CH3C6H4CH(CH3)NH2][CH3C6H4CH(CH3)NH3][PF6] ((p-TEA)(p-TEAH)·PF6) crystallizing in the polar monoclinic C2 space group. The asymmetry… read more here.
Keywords: pf6; highly electrostrictive; salt cocrystal; teah pf6 ... See more keywords