Palladium Allylic Complexes with enantiopure bis(diamidophosphite) ligands bearing a cyclohexane-1,2-diamine skeleton as catalysts in the allylic substitution reaction
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DOI: 10.1016/j.jorganchem.2016.12.007
Abstract: Abstract A series of cationic allyl palladium complexes [Pd(η3-CH3-C3H5)(P-P)]X (X = PF6, 2a-c, 2e; and X = BPh4, 3a, 3b, 3d, 3e) and [Pd(η3-1,3-Ph2-C3H3)(P-P)]X (X = PF6, 6b; and X = BPh4, 7a) have been prepared. The bis(diamidophosphite) ligands (P-P) contain a diazaphospholidine… read more here.
Keywords: diamidophosphite ligands; allylic substitution; palladium; pf6 bph4 ... See more keywords