Ruthenium-based PACT agents based on bisquinoline chelates: synthesis, photochemistry, and cytotoxicity
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Biological Inorganic Chemistry"
DOI: 10.1007/s00775-021-01882-8
Abstract: Graphic abstract The known ruthenium complex [Ru(tpy)(bpy)(Hmte)](PF6)2 ([1](PF6)2, where tpy = 2,2’:6’,2″-terpyridine, bpy = 2,2’-bipyridine, Hmte = 2-(methylthio)ethanol) is photosubstitutionally active but non-toxic to cancer cells even upon light irradiation. In this work, the two analogs complexes [Ru(tpy)(NN)(Hmte)](PF6)2, where NN = 3,3'-biisoquinoline (i-biq,… read more here.
Keywords: ruthenium; pf6; pf6 pf6; cytotoxicity ... See more keywords
CO Release from N,C,S-Pincer Iron(III) Carbonyl Complexes Induced by Visible-to-NIR Light Irradiation: Mechanistic Insight into Effects of Axial Phosphorus Ligands.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b01407
Abstract: Light-induced CO release from newly synthesized N,C,S-pincer iron(III) carbonyl complexes with two phosphorus ligands- trans-[Fe(L-κ3 N,C,S)(CO)(PR2R')2]PF6 ([1]PF6, R = Me, R' = Ph; [2]PF6, R = R' = Me; [3]PF6, R = R' = OEt)-were… read more here.
Keywords: pf6; pf6 pf6; carbonyl complexes; iii carbonyl ... See more keywords
Characterization and photocatalytic behavior of 2,9-di(aryl)-1,10-phenanthroline copper(i) complexes.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt00400a
Abstract: The synthesis, characterization, photophysical properties, theoretical calculations, and catalytic applications of 2,9-di(aryl)-1,10-phenanthroline copper(i) complexes are described. Specifically, this study made use of di(aryl)-1,10-phenanthroline ligands including 2,9-di(4-methoxyphenyl)-1,10-phenanthroline (1), 2,9-di(4-hydroxyphenyl)-1,10-phenanthroline (2), 2,9-di(4-methoxy-3-methylphenyl)-1,10-phenanthroline (3), and 2,9-di(4-hydroxy-3-methylphenyl)-1,10-phenanthroline (4). The… read more here.
Keywords: copper complexes; aryl phenanthroline; pf6 pf6; phenanthroline ... See more keywords