PNP-Chelated and -Bridged Diiron Dithiolate Complexes Fe2(μ-pdt)(CO)4{(Ph2P)2NR} Together with Related Monophosphine Complexes for the [2Fe]H Subsite of [FeFe]-Hydrogenases: Preparation, Structure, and Electrocatalysis
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DOI: 10.1021/acs.organomet.8b00030
Abstract: As the [2Fe]H subsite models of [FeFe]-hydrogenases, a series of PNP-chelated and -bridged diiron dithiolate complexes 1a–f and 2a–f together with the three related monophosphine complexes 3a–c were prepared by the selective substitutions of the… read more here.
Keywords: pnp; fe2 pdt; complexes fe2; pnp chelated ... See more keywords