Transmetallation of bis(6-diphenylphosphinoxy-acenapth-5-yl)mercury with tin tetrachloride, antimony trichloride and bismuth trichloride.
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DOI: 10.1039/c9dt00827f
Abstract: We recently communicated (Angew. Chem. Int. Ed., 2018, 57, 5917-5920) the transmetallation of [6-Ph2P(O)-Ace-5-]2Hg (1) with Pb(OAc)4, which, after work-up with HCl in Et2O, provided the first aryl lead trichloride, 6-Ph2P(O)-Ace-5-PbCl3 (2), and 6-Ph2P(O)-Ace-5-HgCl (3).… read more here.
Keywords: transmetallation bis; ph2p ace; thf thf; transmetallation ... See more keywords