Reactions of diphosphine-stabilized Os3 clusters with triphenylantimony: syntheses and structures of new antimony-containing Os3 clusters via Sb–Ph bond cleavage
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DOI: 10.1039/d2ra07284j
Abstract: The reactivity of the trimetallic clusters [Os3(CO)10(μ-dppm)] [dppm = bis(diphenylphosphino)methane] and [HOs3(CO)8{μ3-Ph2PCH2PPh(C6H4-μ2,σ1)}] with triphenylantimony (SbPh3) has been examined. [Os3(CO)10(μ-dppm)] reacts with SbPh3 in refluxing toluene to yield three new triosmium clusters [Os3(CO)9(SbPh3)(μ-dppm)] (1), [HOs3(CO)7(SbPh3){μ3-Ph2PCH2PPh(C6H4-μ2,σ1)}] (2),… read more here.
Keywords: hos3; ph2pch2pph c6h4; dppm; sbph3 ... See more keywords