Syntheses, molecular structures, and spectroscopic properties of manganese(II)/(III) complexes with tetraphenylimidodiphosphinato and bi-pyridine or salicylaldehyde ligands
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DOI: 10.1016/j.ica.2019.119298
Abstract: Abstract Treatment of [Mn(CH3COO)2·4H2O] with two equivalents of K[N(Ph2PO)2] in the presence of one equivalent of 2,2′-bipyridine (bpy) or 5,5′-dimethyl-2,2′-bipyridine(dmbpy) in ethanol resulted in the formation of the mono-nuclear manganese(II) complexes [Mn{η1 O N(Ph2PO)2}{N(Ph2PO)2}(EtOH)(bpy)] (1)… read more here.
Keywords: manganese iii; molecular structures; ph2po; salicylaldehyde ... See more keywords
Syntheses, structures and catalytic properties of new mononuclear terpyridine-manganese(II) complexes with tetraphenylimido-diphosphinate and diphenylphosphinate ligands
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DOI: 10.1080/00958972.2019.1587163
Abstract: Abstract Treatment of manganese(II) acetate tetrahydrate [Mn(CH3COO)2·4H2O] with one equivalent of 2,2′:6′,2′′-terpyridine (terpy) and two equivalents of potassium tetraphenylimido-diphosphinate K[N(Ph2PO)2] in methanol afforded a mononuclear manganese(II) complex, [(terpy)Mn{η1-O-N(Ph2PO)2}2(H2O)] (1), with two terminal [N(Ph2PO)2]– ligands. Interaction… read more here.
Keywords: terpyridine; terpy; 4h2o one; tetraphenylimido diphosphinate ... See more keywords