Synthesis of Type II Ge and Ge-Si Alloyed Clathrates Using Solid-State Electrochemical Oxidation of Zintl Phase Precursors.
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DOI: 10.1021/acs.inorgchem.2c01748
Abstract: Germanium clathrates with the type II structure are open-framework materials that show promise for various applications, but the difficulty of achieving phase-pure products via traditional synthesis routes has hindered their development. Herein, we demonstrate the… read more here.
Keywords: oxidation; phase precursors; synthesis type; zintl phase ... See more keywords