LAUSR

Synthesis, structure and reactivity of a carborane-fused silylene 1-{[PhC(NtBu)2]Si}-1,2-C2B10H11

Sign Up to like & get
recommendations!
1 Published in 2018 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2018.02.047

Abstract: Abstract A carborane-fused silylene 1-{[PhC(NtBu)2]Si}-1,2-C2B10H11 (2) has been prepared and structurally characterized from an equimolar reaction of 1-Li-1,2-C2B10H11 with [PhC(NtBu)2]SiCl (1) in Et2O. The reactions of 2 with elemental sulfur and benzophenone afforded the corresponding… read more here.

Keywords: phc ntbu; carborane fused; fused silylene; carborane ... See more keywords

Isolation of Silacycles from the Reactions of a Monochlorosilylene LSi(:)Cl (L = PhC(NtBu)2) with Ethynyl Lithium Salts.

Sign Up to like & get
recommendations!
2 Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c01762

Abstract: The reactions of amidinate silylene chloride LSi(:)Cl (L = PhC(NtBu)2) with TMS- and Ph-ethynyl lithium salts gave rise to silacycles 1 and 4, respectively. The formation of 1 and 4 may undergo cyclo-condensations of transient… read more here.

Keywords: lithium salts; lsi phc; phc ntbu; ethynyl lithium ... See more keywords

Unique Approach to Copper(I) Silylene Chalcogenone Complexes.

Sign Up to like & get
recommendations!
1 Published in 2017 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.6b02833

Abstract: Silylene-S-thione [PhC(NtBu)2Si(═S)N(SiMe3)2] (2) and silylene-Se-selone [PhC(NtBu)2Si(═Se)N(SiMe3)2] (3) compounds were prepared from the silylene [PhC(NtBu)2SiN(SiMe3)2] (1) with 1 equiv of 1/8 S8 and 1 equiv of Se powder, respectively, in high yields. Furthermore, compounds 2 and… read more here.

Keywords: cubr; phc ntbu; copper; silylene ... See more keywords

A neutral vicinal silylene/phosphane supported six-membered C2PSiAu2 ring and a silver(I) complex.

Sign Up to like & get
recommendations!
2 Published in 2022 at "Chemical communications"

DOI: 10.1039/d2cc04163d

Abstract: This work presents the different coordination nature of the bidentate ligand towards gold and silver complexes. The reaction of 1 with AuClSMe2 in dichloromethane resulted in two gold atoms containing six-membered ring PhC(NtBu)2Si-Au⋯Au-PPh2C6H4 (2). Compound… read more here.

Keywords: vicinal silylene; silver; phc ntbu; neutral vicinal ... See more keywords