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Electronic properties of the S = 5/2 Mn(II) complexes [Mn{PhC(O)NP(O)PPh2}(N,N)(NO3)], (N,N) = phenanthroline, neocuproine, 2,2′-bipyridine

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Published in 2021 at "Polyhedron"

DOI: 10.1016/j.poly.2021.115374

Abstract: Abstract The synthesis, as well as the structural and electronic properties of the [Mn(O,O)(N,N)(NO3)] complexes, (O,O) = {PhC(O)NP(O)PPh2}−, (N,N) = phenanthroline (1), neocuproine (2) and 2,2′-bipyridine (3) is reported. The three complexes were structurally characterized by X-ray crystallography, and… read more here.

Keywords: phenanthroline neocuproine; electronic properties; properties complexes; complexes phc ... See more keywords