Articles with "phen" as a keyword



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Aggregation-Induced Electrochemiluminescence and Nitric Oxide Recognition by Halogen Bonding with a Ruthenium(II) Complex.

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Published in 2023 at "ChemPlusChem"

DOI: 10.1002/cplu.202200421

Abstract: In this study, a new strategy for NO detection based on the aggregation-induced electrochemical luminescence (AIECL) of a ruthenium-based complex and the halogen bonding effect was developed. First, [Ru(phen)2(phen-Br2)]2+ (phen:1,10-phenanthroline, phen-Br2:3,8-dibromo-1,10-phenanthroline) was synthesized and exhibited aggregation-induced… read more here.

Keywords: halogen; phen; aggregation induced; halogen bonding ... See more keywords
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Chiral analysis of α‐diimine Ru(II) and Fe(II) complexes by capillary electrophoresis using sulfated cyclodextrins as stereoselectors

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Published in 2017 at "ELECTROPHORESIS"

DOI: 10.1002/elps.201700077

Abstract: CE using randomly highly sulfated α‐, β‐, and γ‐CDs (S‐α‐CD, S‐β‐CD, S‐γ‐CD), sulfobutylether‐β‐CD (SBE‐β‐CD), single isomer (6‐O‐sulfo) α‐, β‐, and γ‐CDs, and their derivatives as stereoselectors was applied to chiral analysis of polypyridyl complexes of… read more here.

Keywords: chiral analysis; complexes capillary; analysis; diimine complexes ... See more keywords
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Dye Adsorption and Fluorescence Sensing Behaviour About Rare Earth-Indole Carboxylic Acid Complexes

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Published in 2018 at "Journal of Inorganic and Organometallic Polymers and Materials"

DOI: 10.1007/s10904-018-0869-9

Abstract: AbstractFive rare earth-indole carboxylic acid complexes: [Eu(IAA)2(phen)2]·NO3 (1) (IAA = indole acetic acid, phen = o-phenanthroline); [Nd(IAA)2(phen)2]·NO3 (2); [Er(IBA)3(phen)](phen)·HNO3·H2O (3) (IBA = indole butyric acid); [Ce(IBA)3(phen)](phen)·HNO3·H2O (4); [Dy(IBA)3(phen)](phen)·HNO3·H2O (5) were synthesized and characterized. Then, we reported their properties as dye adsorption… read more here.

Keywords: adsorption; rare earth; fluorescence sensing; phen ... See more keywords
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Layer-by-layer assembly of luminescent ultrathin films by layered double hydroxides and neutral Al–Phen–Hq

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Published in 2019 at "Research on Chemical Intermediates"

DOI: 10.1007/s11164-019-03749-9

Abstract: Highly transparent ultrathin films (UTFs) were fabricated via layer-by-layer assembly of 110-Phenanthroline monohydrate (Phen)–8-hydroxyquinoline (Hq)–Al3+(Phen–Hq–Al), polyvinyl alchol(PVA) and Mg–Al-layered double hydroxide (LDH)nanosheets. UV–visible absorption and fluorescence spectroscopy showed regular growth of UTFs increasing the numbers… read more here.

Keywords: layered double; layer; layer layer; ultrathin films ... See more keywords
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Neurodevelopmental toxicity assessments of alkyl phenanthrene and Dechlorane Plus co-exposure in zebrafish.

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Published in 2019 at "Ecotoxicology and environmental safety"

DOI: 10.1016/j.ecoenv.2019.05.066

Abstract: Alkyl phenanthrene (A-Phen) and Dechlorane Plus (DP) are ubiquitous environmental pollutants that widely co-exist in the environment. It has been established that both A-Phen and DP elicit neurotoxicity, but the potential interactive toxicity of these… read more here.

Keywords: phen; exposure; alkyl phenanthrene; dechlorane plus ... See more keywords
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Synthesis, structural characterization and photoluminescence property of two Zn2+/In3+-4,4′-oxydiphthalhydrazidate complexes

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Published in 2018 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2018.05.029

Abstract: Abstract Under the hydrothermal conditions, two new 4,4′-oxydiphthalhydrazidate-containing compounds [Zn2(odpth)2(phen)2]·H2O 1 and [In(odpth)(ox)(phen)] 2 (odpth = 4,4′-oxydiphthalhydrazidate, phen = 1,10-phenanthroline, ox = oxalate), were obtained. Note that odpth ligand was derived from the hydrothermal in situ acylation reaction between 4,4′-oxydiphthalic acid… read more here.

Keywords: odpth phen; synthesis structural; photoluminescence; phen ... See more keywords
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Synthesis, crystal structure and photocurrent response property of a copper(II)-organic supramolecular coordination compound based on [Cu4(phen)4(OH)4(H2O)2]4+ cations and [Cu(EDTA)]2− anions

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Published in 2021 at "Inorganica Chimica Acta"

DOI: 10.1016/j.ica.2021.120462

Abstract: Abstract A hydrogen-bonded hexanuclear cluster-based supramolecular coordination compound {[Cu4(phen)4(OH)4(H2O)2][Cu(EDTA)]2·14H2O}n (1) (phen = 1, 10-phenanthroline, EDTA4- = full deprotonated ethylenediamine tetraacetic acid) has been isolated through the self-assembly of aromatic diimine ligand phen and sexadentate ligand EDTA4- with acetate copper(II).… read more here.

Keywords: phen h2o; spectroscopy; phen; cu4 phen ... See more keywords
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Synthesis, characterization, DNA binding, topoisomerase inhibition, and apoptosis induction studies of a novel cobalt(III) complex with a thiosemicarbazone ligand.

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Published in 2019 at "Journal of inorganic biochemistry"

DOI: 10.1016/j.jinorgbio.2019.110907

Abstract: In this study, 9-anthraldehyde-N(4)-methylthiosemicarbazone (MeATSC) 1 and [Co(phen)2(O2CO)]Cl·6H2O 2 (where phen = 1,10-phenanthroline) were synthesized. [Co(phen)2(O2CO)]Cl·6H2O 2 was used to produce anhydrous [Co(phen)2(H2O)2](NO3)33. Subsequently, anhydrous [Co(phen)2(H2O)2](NO3)33 was reacted with MeATSC 1 to produce [Co(phen)2(MeATSC)](NO3)3·1.5H2O·C2H5OH 4. The ligand,… read more here.

Keywords: phen; characterization dna; topoisomerase inhibition; synthesis characterization ... See more keywords
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Therapeutic potential of vanadium complexes with 1,10-phenanthroline ligands, quo vadis? Fate of complexes in cell media and cancer cells.

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Published in 2021 at "Journal of inorganic biochemistry"

DOI: 10.1016/j.jinorgbio.2020.111350

Abstract: VIVO-complexes formulated as [VIVO(OSO3)(phen)2] (1) (phen = 1,10-phenanthroline), [VIVO(OSO3)(Me2phen)2] (2) (Me2phen = 4,7-dimethyl-1,10-phenanthroline) and [VIVO(OSO3)(amphen)2] (3) (amphen = 5-amino-1,10-phenanthroline) were prepared and stability in cell incubation media evaluated. Their cytotoxicity was determined against the A2780 (ovarian), MCF7 (breast) and PC3 (prostate)… read more here.

Keywords: cell media; vivo oso3; phen; cancer cells ... See more keywords
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Synthesis, structure, magnetism, luminescence and DFT analysis of three metal-organic complexes based on 2,5-di(1H-1,2,4-triazol-1-yl)terephthalic acid

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Published in 2021 at "Journal of Solid State Chemistry"

DOI: 10.1016/j.jssc.2021.122368

Abstract: Abstract The three multi-dimensional coordination polymers, [Mn2(μ4-dttpa)(μ6-dttpa)(H2O)2]n(1), {[Co(μ4-dttpa)(H2O)2]·2H2O}n(2), and {[Zn3(μ4-dttpa)2(μ2-dttpa)(phen)2(H2O)2]·2H2O}n(3) (H2dttpa ​= ​2,5-di(1H-1,2,4-triazol-1-yl)terephthalic acid; phen ​= ​1,10- phenanthroline), are successfully synthesized and characterized by X-ray single crystal diffraction, powder X-ray diffraction (PXRD), FT-IR spectra, elemental analysis and thermogravimetric analysis.… read more here.

Keywords: terephthalic acid; triazol terephthalic; structure; dttpa ... See more keywords
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Low-dimensional compounds containing cyanido groups. Part XXXII. Field-induced multiple slow magnetic relaxation in [CoII(dcnm)(H2O)(phen)2](dcnm) complex with dominant easy-plane anisotropy (dcnm = dicyanonitrosomethanide)

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Published in 2017 at "Polyhedron"

DOI: 10.1016/j.poly.2017.08.009

Abstract: Abstract Ionic cobalt(II) complex [Co(dcnm)(H2O)(phen)2](dcnm) (1) (dcnm = dicyanonitrosomethanide, phen = 1,10-phenantroline) has been prepared by a diffusion technique. Its structure is formed by [Co(dcnm)(H2O)(phen)2]+ complex cation and free dcnm counterion in the lattice which acts as a hydrogen-bond… read more here.

Keywords: h2o phen; relaxation; dcnm; phen ... See more keywords