Open-Shell Germylene Stabilized by a Phenalenyl-Based Ligand.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00583
Abstract: An open-shell germylene 1 stabilized by a phenalenyl-based bidentate ligand was synthesized and characterized. Because of the high thermal stability originating from spin delocalization over the phenalenyl moiety, it was possible to isolate compound 1… read more here.
Keywords: shell germylene; germylene stabilized; stabilized phenalenyl; open shell ... See more keywords
Synthesis, Structure, and Reactivity of a Gallylene Derivative Bearing a Phenalenyl-Based Ligand.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c00697
Abstract: Phenalenyl-based N,N-bidentate ligand-stabilized monovalent gallium(I) complex 1 was synthesized and characterized by NMR spectroscopies, single-crystal X-ray diffraction, and theoretical calculations. In solution, complex 1 has a high thermal stability at 80 °C, with an absorption… read more here.
Keywords: derivative bearing; gallylene derivative; synthesis structure; phenalenyl based ... See more keywords
A phenalenyl-based nickel catalyst for the hydroboration of olefins under ambient conditions.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt00468h
Abstract: In this report, nickel-catalyzed hydroboration of vinylarenes and aliphatic alkenes is investigated. The non-innocent phenalenyl ligand moiety in the nickel complex Ni(PLY)2(THF)2 (1) was utilized as an electron reservoir for the selective hydroboration reaction in… read more here.
Keywords: based nickel; catalyst hydroboration; nickel catalyst; ambient conditions ... See more keywords