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Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01791
Abstract: A new ligand, namely, 2-(5-(pyren-1-yl)pentyl)-9-methyl-1,10-phenanthroline, as well as new bis(2,9-dialkyl-1,10-phenanthroline)copper(II) complexes were designed, which were immobilized on multiwalled carbon nanotube (MWCNT) electrodes. These complexes show a high tendency of autoreduction into their copper(I) form according…
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Keywords:
copper;
phenanthroline;
dialkyl phenanthroline;
phenanthroline copper ... See more keywords
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Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b02740
Abstract: In recent years, copper(I/II) complexes have emerged as alternative redox shuttles in dye-sensitized solar cells (DSSCs), exhibiting more positive redox potential than iodine- and cobalt-based redox shuttles. In particular, copper(I/II) complexes with 1,10-phenanthroline- or 2,2'-bipyridyl-based…
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Keywords:
copper complexes;
redox;
copper;
redox shuttles ... See more keywords
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Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt00400a
Abstract: The synthesis, characterization, photophysical properties, theoretical calculations, and catalytic applications of 2,9-di(aryl)-1,10-phenanthroline copper(i) complexes are described. Specifically, this study made use of di(aryl)-1,10-phenanthroline ligands including 2,9-di(4-methoxyphenyl)-1,10-phenanthroline (1), 2,9-di(4-hydroxyphenyl)-1,10-phenanthroline (2), 2,9-di(4-methoxy-3-methylphenyl)-1,10-phenanthroline (3), and 2,9-di(4-hydroxy-3-methylphenyl)-1,10-phenanthroline (4). The…
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Keywords:
copper complexes;
aryl phenanthroline;
pf6 pf6;
phenanthroline ... See more keywords