Bioproduction of natural phenethyl acetate, phenylacetic acid, ethyl phenylacetate, and phenethyl phenylacetate from renewable feedstock.
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DOI: 10.1002/cssc.202102645
Abstract: Natural phenethyl acetate (PEA), phenylacetic acid (PAA), ethyl phenylacetate (Et-PA), and phenethyl phenylacetate (PE-PA) are highly wanted aroma chemicals, but with limited availability and high price. Here we developed green, sustainable, and efficient bioproduction of… read more here.
Keywords: phenethyl acetate; phenethyl; phenylacetate; ethyl phenylacetate ... See more keywords
Enzymatic synthesis of 2-phenethyl acetate in water catalyzed by an immobilized acyltransferase from Mycobacterium smegmatis
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DOI: 10.1039/d1ra07946h
Abstract: Although water is an ideal green solvent for organic synthesis, it is difficult for most biocatalysts to carry out transesterification reactions in water because of the reversible hydrolysis reaction. 3D structural characteristics and the microenvironment… read more here.
Keywords: reaction; phenethyl acetate; water; synthesis ... See more keywords
Chemoenzymatic Total Synthesis of (+)-10-Keto-Oxycodone from Phenethyl Acetate †
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DOI: 10.3390/molecules24193477
Abstract: The total synthesis of (+)-10-keto-oxycodone was attained from phenethyl acetate in a stereoselective manner. Absolute stereochemistry was established via enzymatic dihydroxylation of phenethyl acetate with the recombinant strain JM109 (pDTG601A) that furnished the corresponding cis-cyclohexadienediol… read more here.
Keywords: total synthesis; phenethyl acetate; synthesis keto; keto ... See more keywords