Pd-Catalyzed Atroposelective C-H Acyloxylation Enabling Access to an Axially Chiral Biaryl Phenol Organocatalyst.
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DOI: 10.1021/acs.orglett.2c01981
Abstract: Herein, we present the Pd(II)-catalyzed atroposelective C-H acyloxylation strategy for the assembly of biaryl aldehyde atropoisomers using readily available amino acids as the catalytic auxiliary and chiral pool. This strategy exhibits a broad substrate scope… read more here.
Keywords: catalyzed atroposelective; phenol organocatalyst; atroposelective acyloxylation;