Electronic Effect on Phenoxide Migration at a Nickel(II) Center Supported by a Tridentate Bis(phosphinophenyl)phosphido Ligand.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c03557
Abstract: A phosphide nickel(II) phenoxide pincer complex (2) reacts with CO(g) to give a pseudo-tetrahedral nickel(0) monocarbonyl complex (3) possessing a phosphinite moiety. This metal-ligand cooperative (MLC) transformation occurs with a (PPP)Ni scaffold (PPP- = P[2-PiPr2-C6H4]2-),… read more here.
Keywords: nickel; phenolate; ligand; center ... See more keywords
Isolation of monomeric copper(II) phenolate selenoether complexes using chelating ortho-bisphenylselenide-phenolate ligands and their electrocatalytic hydrogen gas evolution activity.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00678b
Abstract: A series of novel copper(II) phenolate selenoether complexes have been synthesized and structurally characterized for the first time from copper(I) phenanthroline and various substituted ortho-bisphenylselenide-phenol chelating ligands. The synthesized complexes exhibit Jahn-Teller distortion in their… read more here.
Keywords: phenolate selenoether; phenolate; geometry; copper phenolate ... See more keywords
Aluminium complexes containing indolyl-phenolate ligands as catalysts for ring-opening polymerization of cyclic esters
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DOI: 10.1039/d2ra05112e
Abstract: A family of aluminium complexes supported by mono-anionic indolyl-phenolate ligands are described. Reactions of indolyl-phenolate based ligand precursors, IndHPhROH, with 1.0 or 0.5 equivalents of AlMe2Cl in toluene afforded aluminium indolyl-phenolate complexes 1–4 and aluminium… read more here.
Keywords: indolyl phenolate; phenolate; aluminium complexes; phenolate ligands ... See more keywords