Prolinol‐derived phenoxy‐amidine titanium complexes in asymmetric silylcyanation of aldehydes
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DOI: 10.1002/ejic.202400405
Abstract: Three new tridentate phenoxy‐amidine ligands (FA) have been prepared via the ring‐opening of benzoxazole by 2‐(methylamino)ethanol, L‐prolinol and L‐diphenylprolinol. Coordination studies of these FA ligands with Ti have led to the synthesis of the complexes… read more here.
Keywords: asymmetric silylcyanation; phenoxy amidine; prolinol derived; derived phenoxy ... See more keywords
Al and Zn phenoxy-amidine complexes for lactide ROP catalysis.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt01216f
Abstract: We report the synthesis of a new generation of phenoxy-amidine ligands based on an aryloxy moiety possessing an ortho-N-linked trisubstituted amidine. The reaction of the phenol-amidine proligands with aluminum and zinc alkyls gave mono- or… read more here.
Keywords: amidine; lactide rop; ligated complexes; phenoxy amidine ... See more keywords