Sulfate radical induced degradation of β2-adrenoceptor agonists salbutamol and terbutaline: Phenoxyl radical dependent mechanisms.
Sign Up to like & getrecommendations! Published in 2017 at "Water research"
DOI: 10.1016/j.watres.2017.07.025
Abstract: The present study investigated the reactivity and oxidation mechanisms of salbutamol (SAL) and terbutaline (TBL), two typical β2-adrenoceptor agonists, towards sulfate radical (SO4-) by using photo-activated persulfate (PS). The reaction pathways and mechanisms were proposed… read more here.
Keywords: degradation; sulfate radical; phenoxyl; adrenoceptor agonists ... See more keywords
In Situ-Formed Phenoxyl Radical on the CuO Surface Triggers Efficient Persulfate Activation for Phenol Degradation.
Sign Up to like & getrecommendations! Published in 2021 at "Environmental science & technology"
DOI: 10.1021/acs.est.1c03758
Abstract: Transition-metal oxide (MxOy)-based persulfate (PDS) activation processes have demonstrated enormous potential for pollutant degradation in water purification. However, the mechanistic insight of PDS activation by a MxOy catalyst concerning the mediate role of the organic… read more here.
Keywords: degradation; cuo; surface; phenol ... See more keywords
Non-innocent redox behavior of CuII-p-dimethylaminophenolate complexes: formation and characterization of the CuI-phenoxyl radical species.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc01409b
Abstract: Cu complexes with p-dimethylaminophenolate ligands were synthesized by the reaction of CuII ions with the ligands under inert gas atmosphere and characterized. The complexes showed a valence state change from CuII-phenolate to CuI-phenoxyl radical on… read more here.
Keywords: cui phenoxyl; radical species; cuii; phenoxyl radical ... See more keywords
π–π Stacking Interaction of Metal Phenoxyl Radical Complexes
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27031135
Abstract: π–π stacking interaction is well-known to be one of the weak interactions. Its importance in the stabilization of protein structures and functionalization has been reported for various systems. We have focused on a single copper… read more here.
Keywords: metal phenoxyl; interaction metal; phenoxyl radical; interaction ... See more keywords