Effect of Na+ and K+ on the cucurbituril-mediated hydrolysis of a phenyl acetate.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc00772j
Abstract: The environment around the active site affects the catalytic activity of enzymes. Studying the cucurbit[7]uril-promoted acid hydrolysis of a cationic phenyl acetate derivative, we found that the hydrophobic cavity of the macrocycle screens the reaction… read more here.
Keywords: phenyl acetate; mediated hydrolysis; effect cucurbituril; cucurbituril mediated ... See more keywords
Crystal structures of (E)-4-[1-(2-carbamothioylhydrazinylidene)ethyl]phenyl acetate and (E)-4-[1-(2-carbamothioylhydrazinylidene)ethyl]phenyl benzoate
Sign Up to like & getrecommendations! Published in 2017 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989016018983
Abstract: In the title compounds, the thiosemicarbazone group adopts an extended conformation, and there is a short N—H⋯N contact present forming an S(5) ring motif. In the crystals of both compounds, molecules are linked by pairs… read more here.
Keywords: structures carbamothioylhydrazinylidene; crystal structures; carbamothioylhydrazinylidene ethyl; phenyl acetate ... See more keywords
Crystal structures of methyl 3,5-dimethylbenzoate, 3,5-bis(bromomethyl)phenyl acetate and 5-hydroxybenzene-1,3-dicarbaldehyde
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DOI: 10.1107/s2056989022005643
Abstract: The crystals of methyl 3,5-dimethylbenzoate are composed of strands of C—H⋯O=C bonded molecules, which are further arranged into layers. As a result of the presence of two bromomethyl substituents in 3,5-bis(bromomethyl)phenyl acetate, molecular dimers formed… read more here.
Keywords: methyl dimethylbenzoate; phenyl acetate; bis bromomethyl; bromomethyl phenyl ... See more keywords
Skeletal Torsion Tunneling and Methyl Internal Rotation: The Coupled Large Amplitude Motions in Phenyl Acetate
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DOI: 10.3390/molecules27092730
Abstract: The rotational spectrum of phenyl acetate, CH3COOC6H5, is measured using a free jet absorption millimeter-wave spectrometer in the range from 60 to 78 GHz and two pulsed jet Fourier transform microwave spectrometers covering a total… read more here.
Keywords: internal rotation; skeletal torsion; phenyl acetate; large amplitude ... See more keywords