1-t-Butyl-1-phenyl-1-silacyclohexane: Synthesis, conformational analysis in gas and solution by GED, FT-IR and theoretical calculations
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DOI: 10.1016/j.jorganchem.2020.121433
Abstract: Abstract 1-t-Butyl-1-phenyl-1-silacyclohexane 1, the first disubstituted silacyclohexane with the most bulky substituent, t-Bu group, at silicon, was synthesized via the sequence of reactions PhSiCl3 → Ph(Cl)Si(CH2)5 → Ph(t-Bu)Si(CH2)5, and its molecular structure and conformational preferences… read more here.
Keywords: silacyclohexane synthesis; phenyl silacyclohexane; butyl phenyl; gas ... See more keywords