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Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b01047
Abstract: The dicationic complex [CpCo(azpy)(CH3CN)](ClO4)2 1 (azpy = phenylazopyridine) exhibits a reversible two-electron reduction at a very mild potential (-0.16 V versus Fc0/+) in acetonitrile. This behavior is not observed with the analogous bipyridine and pyrazolylpyridine…
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Keywords:
reduction;
multielectron transfer;
two electron;
phenylazopyridine ... See more keywords