Articles with "phenylene ethynylene" as a keyword



Tuning the optical properties of poly(p-phenylene ethynylene) nanoparticles as bio-imaging probes by side chain functionalization.

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Published in 2017 at "Journal of colloid and interface science"

DOI: 10.1016/j.jcis.2017.05.072

Abstract: Conjugated polymers are versatile bio-imaging probes as their optical properties can be readily fine-tuned. In this manuscript, fluorescent conjugated polymer nanoparticles are fabricated using three different poly(p-phenylene ethynylene) (PPE) derivatives. The polymers have the same… read more here.

Keywords: bio imaging; imaging probes; optical properties; poly phenylene ... See more keywords
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Tuning Charge Transport Properties of Asymmetric Molecular Junctions

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Published in 2017 at "Journal of Physical Chemistry C"

DOI: 10.1021/acs.jpcc.7b01105

Abstract: Charge transport characteristics of asymmetric molecules containing a 9,9′-spirobifluorene platform coupled covalently to a phenylene ethynylene linker capped with either a thiol or a nitrile end group are investigated by break junction techniques. It is… read more here.

Keywords: charge transport; transport properties; charge; phenylene ethynylene ... See more keywords

Uniform Continuous and Segmented Nanofibers Containing a π-Conjugated Oligo(p-phenylene ethynylene) Core via “Living” Crystallization-Driven Self-Assembly: Importance of Oligo(p-phenylene ethynylene) Chain Length

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Published in 2020 at "Macromolecules"

DOI: 10.1021/acs.macromol.0c01199

Abstract: π-Conjugated nanofibers of controlled length and composition show promising potential applications from biomedicine to optoelectronics. However, efficient preparation of uniform nanofibers from π-c... read more here.

Keywords: continuous segmented; oligo phenylene; segmented nanofibers; phenylene ethynylene ... See more keywords

One- and Two-Photon Activated Release of Oxaliplatin from a Pt(IV)-Functionalized Poly(phenylene ethynylene).

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Published in 2022 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.2c00859

Abstract: We report a water-soluble poly(phenylene ethynylene) (PPE-Pt(IV)) that is functionalized with oxidized oxaliplatin Pt(IV) units and its use for photoactivated chemotherapy. The photoactivation strategy is based on photoinduced electron transfer from the PPE backbone to… read more here.

Keywords: oxaliplatin; two photon; phenylene ethynylene; release oxaliplatin ... See more keywords

Reorganization Energies for Interfacial Electron Transfer across Phenylene Ethynylene Rigid-Rod Bridges.

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Published in 2022 at "ACS applied materials & interfaces"

DOI: 10.1021/acsami.2c07151

Abstract: A family of three ruthenium bipyridyl rigid-rod compounds of the general form [Ru(bpy)2(LL)](PF6)2 were anchored to mesoporous thin films of tin-doped indium oxide (ITO) nanocrystals. Here, LL is a 4-substituted 2,2-bipyridine (bpy) ligand with varying… read more here.

Keywords: electron transfer; phenylene ethynylene; rigid rod;

Breaking Strong Alkynyl-Phenyl Bonds: Poly(para-phenylene ethynylene)s under Mechanical Stress

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Published in 2024 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.4c08765

Abstract: Stronger chemical bonds withstand higher mechanical forces; thus, the rupture of single bonds is preferred over the rupture of double or triple bonds or aromatic rings. We investigated bond scission in poly(dialkyl-p-phenylene ethynylene)s (PPEs), a… read more here.

Keywords: phenylene ethynylene; breaking strong; strong alkynyl; alkynyl phenyl ... See more keywords