Amidation of aldehydes using mono-cationic half-sandwich rhodium(III) complexes with functionalized phenylhydrazone ligands
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DOI: 10.1016/j.jorganchem.2019.02.018
Abstract: Abstract A series of mono-cationic half-sandwich rhodium(III) complexes have been synthesized in methanol using phenylhydrazone-derived ligands (L1–L6) and the starting precursor [(η5-C5Me5)2Rh2(μ-Cl)2Cl2] in a 2:1 molar ratio. The N,N′-phenylhydrazone complexes have been isolated as tetraphenylborate… read more here.
Keywords: mono cationic; phenylhydrazone; cationic half; half sandwich ... See more keywords