Pd(II)/PhI(OAc)2 promoted direct cross coupling of glucals with aromatic acids.
Sign Up to like & getrecommendations! Published in 2018 at "Carbohydrate research"
DOI: 10.1016/j.carres.2018.03.002
Abstract: A highly efficient oxidative C2-aroyloxylation of D-glucal with aromatic carboxylic acids has been achieved for the first time using 5 mol% Pd(OAc)2 and 1 equiv of PhI(OAc)2 to produce C2-aroyloxyglycals in good yields. The use of… read more here.
Keywords: direct cross; oac promoted; phi oac; promoted direct ... See more keywords
More Than Just Acetates: PhI(OAc)2 Enables C–H Halogenation of Arenes
Sign Up to like & getrecommendations! Published in 2019 at "Chem"
DOI: 10.1016/j.chempr.2019.01.009
Abstract: In this issue of Chem, Nagib and co-workers report an operationally simple approach for direct C–H halogenation of arenes and (hetero)arenes through in situ activation of commercially available PhI(OAc)2. The resulting non-symmetrical iodanes offer chemists new… read more here.
Keywords: halogenation; enables halogenation; oac enables; acetates phi ... See more keywords