Articles with "philicity" as a keyword



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Trans‐philicity (trans‐influence/trans‐effect) ladders for square planar platinum(II) complexes constructed by 35Cl NMR probe

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Published in 2019 at "Journal of Computational Chemistry"

DOI: 10.1002/jcc.26031

Abstract: The unified term of trans‐philicity is proposed to cover the trans‐effect/trans‐influence concepts. NMR trans‐philicity ladders are built for a broad series of square planar trans‐Pt(NH3)2(Cl)L and trans‐Pt(CO)2(Cl)L complexes employing 35Cl NMR probe and quantified by… read more here.

Keywords: trans influence; philicity; square planar; trans philicity ... See more keywords

NMR probe effects on trans-philicity and trans-influence ladders in square planar Pt(ii) complexes

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Published in 2020 at "New Journal of Chemistry"

DOI: 10.1039/d0nj01336f

Abstract: Quantitative trans-philicity ladders for a broad series of ligands in square planar trans-[Pt(PMe3)2(X)L]n (n = 0, 1, 2; X = H, CO, CH3, NH2, OH2, Cl) complexes are built employing the isotropic σiso(SO) X NMR… read more here.

Keywords: trans influence; square planar; philicity trans; trans philicity ... See more keywords