Polysulfide Regulation by Hypervalent Iodine Compounds for Durable and Sustainable Lithium-Sulfur Battery.
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DOI: 10.1002/smll.202106716
Abstract: Herein, a type of hypervalent iodine compound-iodosobenzene (PhIO)-is proposed to regulate the LiPSs electrochemistry and enhance the performance of Li-S battery. PhIO owns the practical advantages of low-cost, commercial availability, environmental friendliness and chemical stability.… read more here.
Keywords: hypervalent iodine; battery; phio; cnt ... See more keywords
Visible Light-Induced Oxidation of Alcohols by a Luminescent Osmium(VI) Nitrido Complex: Evidence for the Generation of PhIO+ as a Highly Active Oxidant in the Presence of PhIO.
Sign Up to like & getrecommendations! Published in 2023 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c00760
Abstract: Although alcohols are readily oxidized by a variety of oxidants, their oxidation by metal nitrido complexes is yet to be studied. We report herein visible-light-induced oxidation of primary and secondary alcohols to carbonyl compounds by… read more here.
Keywords: light induced; phio; nitrido; visible light ... See more keywords
Biomimetic oxidation of cyclic and linear alkanes: high alcohol selectivity promoted by a novel manganese porphyrin catalyst
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DOI: 10.1039/c6nj03072f
Abstract: A novel third-generation metalloporphyrin, chloro-5,10,15,20-tetrakis-(3′-bromine-4′-methoxyphenyl)-2,3,7,8,12,13,17,18-octabromoporphyrinatomanganese(III), [MnIIIBr12T4(-OMe)PPCl], designated as MnBr12Por, was synthesized and characterized. The catalytic activity of the new manganese porphyrin was investigated in the oxidation of cyclohexane, adamantane and n-hexane by iodosylbenzene (PhIO) or… read more here.
Keywords: manganese porphyrin; oxidation; catalyst; phio ... See more keywords