PhIO-Mediated Oxidative C═C Bond Cleavage and Reassembly toward Highly Functionalized Oxazolones.
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DOI: 10.1021/acs.orglett.1c04326
Abstract: An efficient PhIO-mediated oxidative C═C bond cleavage and reassembly of enaminone toward oxazolone with high regioselectivity has been reported. DFT calculations revealed that the reaction proceeded through an oxygen atom transfer, C═C bond cleavage, alkylthio… read more here.
Keywords: phio mediated; mediated oxidative; bond cleavage; oxidative bond ... See more keywords