Lewis Base Catalysis Enables the Activation of Alcohols by means of Chloroformates as Phosgene Substitutes
Sign Up to like & getrecommendations! Published in 2020 at "ChemCatChem"
DOI: 10.1002/cctc.202001175
Abstract: Nucleophilic substitutions (SN) are typically promoted by acid chlorides as sacrificial reagents to improve the thermodynamic driving force and lower kinetic barriers. However, the cheapest acid chloride phosgene (COCl2) is a highly toxic gas. Against… read more here.
Keywords: catalysis enables; enables activation; base catalysis; lewis base ... See more keywords
Adsorption of phosgene on Si-embedded MoS2 sheet and electric field-assisted desorption: insights from DFT calculations
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Materials Science"
DOI: 10.1007/s10853-019-03706-2
Abstract: AbstractIn quest of effective materials and technologies for detecting toxic gas molecules, an attempt is made to detect phosgene gas molecule using MoS2 by employing dispersion corrected density functional theory calculations. Doping Si into the… read more here.
Keywords: adsorption; gas; mos2 sheet; phosgene ... See more keywords
Adsorption of phosgene molecule on the transition metal-doped graphene: First principles calculations
Sign Up to like & getrecommendations! Published in 2017 at "Applied Surface Science"
DOI: 10.1016/j.apsusc.2017.06.229
Abstract: Abstract The adsorption of the phosgene molecule on pristine graphene and transition metal doped (TM = Zr, Mo, Ti, Mn, Fe, Co) graphene is investigated using the first principles method based on density functional theory. The nature… read more here.
Keywords: transition; graphene; doped graphene; phosgene molecule ... See more keywords
Quinoline based colorimetric and “turn-off” fluorescent chemosensor for phosgene sensing in solution and vapor phase
Sign Up to like & getrecommendations! Published in 2021 at "Microchemical Journal"
DOI: 10.1016/j.microc.2021.106334
Abstract: Abstract Phosgene (COCl2) is a kind of extreme poisonous and colorless gas, causing many serious health problems. It’s an urgent requirement to develop a convenient and efficient analytical methods for detection of phosgene in environmental… read more here.
Keywords: fluorescent chemosensor; turn; phosgene; quinoline based ... See more keywords
Ruthenium(II) Polypyridine Complex-Based Aggregation-Induced Emission Luminogen for Rapid and Selective Detection of Phosgene in Solution and in the Gas Phase.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c02987
Abstract: A bis-heteroleptic ruthenium(II) complex, Ru-1, of 4,7-bis(2-aminoethylamino)-1,10-phenanthroline for selective "turn-on" detection of highly toxic chemical warfare agent phosgene is presented. Probe Ru-1 exhibits aggregation-induced emission (AIE), and the restricted intramolecular motion is responsible for the… read more here.
Keywords: emission; reaction; phosgene; microscopy ... See more keywords
Metal-Decorated Phthalocyanine Monolayer as a Potential Gas Sensing Material for Phosgene: A First-Principles Study
Sign Up to like & getrecommendations! Published in 2022 at "ACS Omega"
DOI: 10.1021/acsomega.2c02548
Abstract: Research into a gas sensing material with excellent performance to detect or remove toxic phosgene (COCl2) is of great significance to environmental and biological protection. In the present work, the adsorption performance of COCl2 on… read more here.
Keywords: gas sensing; adsorption; phosgene; cocl2 ... See more keywords
Phosgene use in World War 1 and early evaluations of pathophysiology
Sign Up to like & getrecommendations! Published in 2019 at "Journal of the Royal Army Medical Corps"
DOI: 10.1136/jramc-2018-001072
Abstract: World War 1 ended 100 years ago. The aftermath included the consolidation of significant advances in medical care of casualties. Some of these advances were made in the care of chemical casualties, in particular the… read more here.
Keywords: phosgene use; world war; phosgene;
Comprehensive Analysis of the Profiles of Differentially Expressed mRNAs, lncRNAs, and circRNAs in Phosgene-Induced Acute Lung Injury
Sign Up to like & getrecommendations! Published in 2021 at "BioMed Research International"
DOI: 10.1155/2021/6278526
Abstract: Phosgene exposure can cause acute lung injury (ALI), for which there is no currently available effective treatment. Mesenchymal stem cells (MSCs) which have been proven to have therapeutic potential and be helpful in the treatment… read more here.
Keywords: mrnas lncrnas; lncrnas circrnas; phosgene induced; acute lung ... See more keywords
Acetyl Cellulose Film with 18-crown-6 Ether for Colorimetric Phosgene Detection.
Sign Up to like & getrecommendations! Published in 2022 at "Acta chimica Slovenica"
DOI: 10.17344/acsi.2021.7092
Abstract: The use of a cellulose detection film as a carrier for a colorimetric sensor to detect phosgene and allied compounds to be evaluated primarily visually is studied. For the case study, a benzimidazole-rhodamine dye and… read more here.
Keywords: phosgene; film; detection; detection film ... See more keywords
Chronic Low-dose Exposure to Highly Toxic Gas Phosgene and Its Effect on Peak Expiratory Flow Rate
Sign Up to like & getrecommendations! Published in 2022 at "Indian Journal of Occupational and Environmental Medicine"
DOI: 10.4103/ijoem.ijoem_417_20
Abstract: Introduction: Phosgene is a highly toxic gas causing irritation of the airways and eyes though at high dose exposure. The effect on airways can be assessed by peak expiratory flow rate (PEFR) which is a… read more here.
Keywords: chronic low; phosgene; dose exposure; exposure ... See more keywords