Synthesis of Trapen Ligand-Based U(IV) and Th(IV) 2-Phosphaethynolate Complexes and Comparison of Covalency with Corresponding Ti(IV) Analogues.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02263
Abstract: The involvement of the 2-phosphaethynolate anion species with ambident nucleophilic properties serves as an essential protocol for synthesizing oxygen-bound or phosphorus-bound complexes. This work mainly describes the synthesis and characterization of U, Th, and Ti… read more here.
Keywords: synthesis trapen; covalency; phosphaethynolate; phosphaethynolate complexes ... See more keywords
An isolable magnesium diphosphaethynolate complex.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c7dt04539e
Abstract: The reaction of magnesium chloride with two equivalents of sodium phosphaethynolate, Na[OCP]ยท(dioxane)2.5 (1), yields a magnesium diphosphaethynolate complex, [(THF)4Mg(OCP)2] (3). The formation of compound 3 goes through a monosubstituted chloromagnesium phosphaethynolate Mg(OCP)Cl (2). The structure… read more here.
Keywords: magnesium diphosphaethynolate; diphosphaethynolate complex; isolable magnesium; phosphaethynolate ... See more keywords