A Tautomeric λ3/λ5-Phosphane Pair and Its Ambiphilic Reactivity.
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DOI: 10.1021/acs.inorgchem.9b00076
Abstract: The central phosphorus atom of a novel hydroxyl-functionalized triarylphosphane was shown to reversibly insert into one of the molecule's O-H bonds, which forms the basis for a tautomeric λ3/λ5-phosphane equilibrium. For the first time, this… read more here.
Keywords: tautomeric phosphane; equilibrium; reactivity; pair ambiphilic ... See more keywords