Spectroscopic Identification of Trifluorosilylphosphinidene and Isomeric Phosphasilene and Silicon Trifluorophosphine Complex
Sign Up to like & getrecommendations! Published in 2024 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.4c00135
Abstract: The perfluorinated silylphosphinidene, F3SiP, in the triplet ground state is generated by the reaction of laser-ablated silicon atoms with PF3 in solid neon and argon matrices. The reactions proceed with the initial formation of a… read more here.
Keywords: trifluorosilylphosphinidene; phosphasilene; silicon trifluorophosphine; state ... See more keywords
Phosphasilene mediated CO activation and deoxygenative homo coupling of CO molecules in reactions with metal carbonyls
Sign Up to like & getrecommendations! Published in 2024 at "Chemical Science"
DOI: 10.1039/d4sc05491a
Abstract: Herein, we report the synthesis of a new sterically demanding hyper-coordinate phosphasilene (Mes*PSi(SiMe3)(PhC(NtBu)2) (1) and its unprecedented reactivity with metal carbonyls (M = Fe, Mo, W). The reaction of 1 with Fe(CO)5 involves the deoxygenative… read more here.
Keywords: activation deoxygenative; mediated activation; phosphasilene; phosphasilene mediated ... See more keywords