Phosphasilene mediated CO activation and deoxygenative homo coupling of CO molecules in reactions with metal carbonyls
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DOI: 10.1039/d4sc05491a
Abstract: Herein, we report the synthesis of a new sterically demanding hyper-coordinate phosphasilene (Mes*PSi(SiMe3)(PhC(NtBu)2) (1) and its unprecedented reactivity with metal carbonyls (M = Fe, Mo, W). The reaction of 1 with Fe(CO)5 involves the deoxygenative… read more here.
Keywords: activation deoxygenative; mediated activation; phosphasilene; phosphasilene mediated ... See more keywords