Hydrophobic Amplification Enabled High-Turnover Phosphazene Superbase Catalysis.
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DOI: 10.1002/cssc.202200634
Abstract: β-Sulfido sulfonyl fluoride and its derivatives have been gaining attention recently in the fields of medicinal chemistry and material science. The conventional method for the synthesis of functionalized alkyl sulfonyl fluorides requires several chemical transformations.… read more here.
Keywords: high turnover; hydrophobic amplification; phosphazene superbase; sulfonyl ... See more keywords
Investigation of Phosphazene Superbase Interactions with [PCl2N]3.
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DOI: 10.1021/acs.inorgchem.4c03002
Abstract: In this study, the reaction between phosphazene superbases and a chlorophosphazene trimer ([PCl2N]3) has been investigated. In this room temperature reaction, the phosphazene superbase (Me2N)3PN(Me2N)2P═NEt, commonly known as P2Et, was shown to behave as a… read more here.
Keywords: reaction; phosphazene superbase; superbase interactions; investigation phosphazene ... See more keywords